Thermodynamic dataset of Sakurajima key basalt and andesite

by Isoji Miyagi (GSJ)


This database provides thermodynamic calculation results for the key magmas of Sakurajima Volcano. A series of thermodynamic data has been obtained using the Rhyolite-MELTS software on the magma compositions of key basalt and andesite of Sakurajima volcano (B_EastBay and A_1976_0525 with SiO2 47 and 59 wt. % and with K2O 0.5 and 1.5 wt. %, respectively). The results are visualized as contour diagrams plotted on temperature–pressure planes comprising 44,415 PNG images. These diagrams are interlinked via hypertext, and the associated numerical data are organized in an SQLite3 database, with guidance on extracting relevant information.

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The parameters include the amount and chemical compositions of minerals and melt in equilibrium at some P, T, fO2, and H2O concentrations. These parameters were obtained using the Rhyolite-MELTS (v 1.1.0) program (Gualda et al., 2012; Asimow and Ghiorso, 1998; Ghiorso and Sack, 1995) over the range of pressure from 1 atmosphere to 860 MPa with 1-10 MPa step, temperature from 700 to 1400 deg-C with 1 deg-C step, oxygen fugacity FMQ+1 log unit, water concentration 0.0, 0.2, 0.4, 0.6, 0.8, 1.0, 1.2, 1.4, 1.6, 1.8, 2.0; 2.2, 2.4, 2.6, 2.8, 3.0, 3.2, 3.4, 3.6, 3.8, 4.0, 4.2, 4.4, 4.6, 4.8, 5.0, 5.2, 5.4, 5.6, 5.8, 6.0, 6.2, 6.4, 6.6, 6.8, 7.0, 7.2, 7.4, 7.6, 7.8, 8.0 wt.% H2O, and CO2 0.001, 0.01, 0.1, and 1 wt.%. Since the Rhyolite-MELTS program outputs huge quantities of numerical values, I summarized them into a suite of contour maps on a pressure-temperature plane using the GMT program (Wessel and Smith, 1998) and utilized them cross-linked to develop a convenient tool.

In addition, you can extract numerical data from the plot using the sqlite3 command, following the Command Tips on the graph pages.


Figure 1. K2O - SiO2 variation diagram of the eruptive products of Sakurajima volcano. B: whole-rock chemical composition of primitive basalt from the eastern Kagoshima bay (Yamaguchi, 1975). A: whole-rock chemical composition of mafic end-member andesitic volcanic ejecta of 25 May 1976 (Aramaki, 1980). Red open circles (Melt): interstitial glass of matrix and melt inclusions in phenocrysts (Miyagi et al., 2010, 2013; Miyagi unpublished data). Black open circles (WR): whole-rock chemical composition (Yamaguchi, 1975; Aramaki, 1975, 1977, 1980; Fukuyama and Ono, 1981; Aramaki and Masui, 1982; Aramaki and Kobayashi, 1986, 1988; Kobayashi and Aramaki, 1989; Yanagi+1991 Fujii and Kobayashi, 1995; Miki et al., 2003). Purple dots (Xtal): chemical composition of phenocrysts and micro-phenocryst.

Starting material of the MELTS computations
No.SiO2TiO2Al2O3tFeOMnOMgOCaONa2OK2OP2O5SClFTotalwhatComment
B_EastBay47.050.7820.0910.260.075.6613.21.980.480.1100099.68No.092 Yamaguchi_1975WR, Basalt of the eastern Kagoshima bay
A_1976_0525590.7816.66.840.153.117.933.161.480.1900099.24008 Aramaki_1980WR, 25 May 1976 volcanic ejecta
WR: Whole-rock chemical composition Pfd: Pyroclastic flow deposit.


An example of citation:

Miyagi (2025) Thermodynamic dataset of Sakurajima key basalt and andesite https://doi.org/10.57765/2003426